Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment.
The first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexe...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2006
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| _version_ | 1797058071306960896 |
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| author | Jones, C Aldridge, S Gans-Eichler, T Stasch, A |
| author_facet | Jones, C Aldridge, S Gans-Eichler, T Stasch, A |
| author_sort | Jones, C |
| collection | OXFORD |
| description | The first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexes, [CpFe(CO)2M(X)(amid)] (4 examples) have been crystallographically characterised and subject to halide abstraction reactions. In one case, the cationic complex, [CpFe(CO)2Ga(OEt2){(CyN)2CBut}][BArf4], was isolated and crystallographically characterised. A hydrolysis product of this complex, [{CpFe(CO)2Ga[(CyN)2CBut]}2(micro-OH)][BArf4], was also isolated in low yield from this reaction and structurally characterised. |
| first_indexed | 2024-03-06T19:45:25Z |
| format | Journal article |
| id | oxford-uuid:22231ab6-a4e9-4edb-9fed-a86ef00f108d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:45:25Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:22231ab6-a4e9-4edb-9fed-a86ef00f108d2022-03-26T11:37:04ZSynthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:22231ab6-a4e9-4edb-9fed-a86ef00f108dEnglishSymplectic Elements at Oxford2006Jones, CAldridge, SGans-Eichler, TStasch, AThe first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexes, [CpFe(CO)2M(X)(amid)] (4 examples) have been crystallographically characterised and subject to halide abstraction reactions. In one case, the cationic complex, [CpFe(CO)2Ga(OEt2){(CyN)2CBut}][BArf4], was isolated and crystallographically characterised. A hydrolysis product of this complex, [{CpFe(CO)2Ga[(CyN)2CBut]}2(micro-OH)][BArf4], was also isolated in low yield from this reaction and structurally characterised. |
| spellingShingle | Jones, C Aldridge, S Gans-Eichler, T Stasch, A Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title | Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title_full | Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title_fullStr | Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title_full_unstemmed | Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title_short | Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment. |
| title_sort | synthesis and characterisation of complexes of group 13 metal amidinate heterocycles with the cpfe co 2 fragment |
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