Studies of ansa-bis(cyclopentadienyl)tungsten derivatives

Studies of ansa-bis(cyclopentadienyl)tungsten derivatives

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The new compounds [W{(h-C5H4)X(h-C5H4)}Cl2] 1, [W{(h-C5H4)X(h-C5H4)}Me2] 2, [W{(h-C5H4)SiMe2-(h-C5H4)}(SPh)2] 3, [W{(h-C5H4)X(h-C5H4)}H(Cl)] 4, [W{(h-C5H4)X(h-C5H4)}H2] 5 and [W{(h-C5H4)-X(h-C5H4)}H3]1Y2 6, where X = SiMe2, SiEt2 or CMe2CMe2, and Y = BF4 or Cl, have been prepared. The crystal struct...

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Detalles Bibliográficos
Main Authors: Conway, S, Dijkstra, T, Doerrer, L, Green, J, Green, M, Stephens, A
Formato: Journal article
Idioma:English
Publicado: Royal Society of Chemistry 1998
Subjects:
Inorganic chemistry
Organometallic Chemistry
Chemistry & allied sciences
Descripción
Summary:The new compounds [W{(h-C5H4)X(h-C5H4)}Cl2] 1, [W{(h-C5H4)X(h-C5H4)}Me2] 2, [W{(h-C5H4)SiMe2-(h-C5H4)}(SPh)2] 3, [W{(h-C5H4)X(h-C5H4)}H(Cl)] 4, [W{(h-C5H4)X(h-C5H4)}H2] 5 and [W{(h-C5H4)-X(h-C5H4)}H3]1Y2 6, where X = SiMe2, SiEt2 or CMe2CMe2, and Y = BF4 or Cl, have been prepared. The crystal structures of [W{(h-C5H4)X(h-C5H4)}Me2] (X = SiMe2 or CMe2CMe2) have been determined.

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