Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)

Widespread deposition of organic-rich shales during the Late Cretaceous Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) occurred during a period of significant global paleo-environmental and geochemical change. It has been proposed that an increase in nutrient input to the ocean during OAE 2 was the key m...

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Main Authors: Sweere, T, Dickson, A, Jenkyns, H, Porcelli, D, Elrick, M, van den Boorn, S, Henderson, G
Format: Journal article
Published: Geological Society of America 2018
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author Sweere, T
Dickson, A
Jenkyns, H
Porcelli, D
Elrick, M
van den Boorn, S
Henderson, G
author_facet Sweere, T
Dickson, A
Jenkyns, H
Porcelli, D
Elrick, M
van den Boorn, S
Henderson, G
author_sort Sweere, T
collection OXFORD
description Widespread deposition of organic-rich shales during the Late Cretaceous Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) occurred during a period of significant global paleo-environmental and geochemical change. It has been proposed that an increase in nutrient input to the ocean during OAE 2 was the key mechanism that generated and sustained high rates of organic-matter burial over time scales of 103–105 yr. Zinc is a bio-essential micronutrient and the proportion of Zn burial in oxic sediments relative to burial in organic-rich continental margin sediments is reflected in its seawater isotope composition. The first Zn-isotope records dating from the Cretaceous are presented here from three coeval carbonate successions: two from Europe (southern England and southern Italy) and one from southern Mexico. The new data show reproducible stratigraphic Zn-isotope patterns in spatially and lithologically diverse carbonate successions. Excursions to lower Zn-isotope values may be linked to the input of magmatic Zn, changes in the proportion of Zn burial into organic-rich sediments, and the liberation of previously buried Zn during an episode of widespread seafloor re-oxygenation during OAE 2 (the Plenus Cold Event).
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spelling oxford-uuid:22283c0a-a13a-44b8-a3da-adf52b447aca2022-03-26T11:37:11ZIsotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:22283c0a-a13a-44b8-a3da-adf52b447acaSymplectic Elements at OxfordGeological Society of America2018Sweere, TDickson, AJenkyns, HPorcelli, DElrick, Mvan den Boorn, SHenderson, GWidespread deposition of organic-rich shales during the Late Cretaceous Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) occurred during a period of significant global paleo-environmental and geochemical change. It has been proposed that an increase in nutrient input to the ocean during OAE 2 was the key mechanism that generated and sustained high rates of organic-matter burial over time scales of 103–105 yr. Zinc is a bio-essential micronutrient and the proportion of Zn burial in oxic sediments relative to burial in organic-rich continental margin sediments is reflected in its seawater isotope composition. The first Zn-isotope records dating from the Cretaceous are presented here from three coeval carbonate successions: two from Europe (southern England and southern Italy) and one from southern Mexico. The new data show reproducible stratigraphic Zn-isotope patterns in spatially and lithologically diverse carbonate successions. Excursions to lower Zn-isotope values may be linked to the input of magmatic Zn, changes in the proportion of Zn burial into organic-rich sediments, and the liberation of previously buried Zn during an episode of widespread seafloor re-oxygenation during OAE 2 (the Plenus Cold Event).
spellingShingle Sweere, T
Dickson, A
Jenkyns, H
Porcelli, D
Elrick, M
van den Boorn, S
Henderson, G
Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title_full Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title_fullStr Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title_full_unstemmed Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title_short Isotopic evidence for changes in the zinc cycle during Oceanic Anoxic Event 2 (Late Cretaceous)
title_sort isotopic evidence for changes in the zinc cycle during oceanic anoxic event 2 late cretaceous
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AT jenkynsh isotopicevidenceforchangesinthezinccycleduringoceanicanoxicevent2latecretaceous
AT porcellid isotopicevidenceforchangesinthezinccycleduringoceanicanoxicevent2latecretaceous
AT elrickm isotopicevidenceforchangesinthezinccycleduringoceanicanoxicevent2latecretaceous
AT vandenboorns isotopicevidenceforchangesinthezinccycleduringoceanicanoxicevent2latecretaceous
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