Ferrocenyl substituted carboranes: synthesis and characterisation
The reaction between ethynyl ferrocene and decaborane affords the new ferrocenyl substituted carborane 1-{Fc}-1,2-closo-C2B10H11 1 [Fc=(η5-C5H4)Fe(η5-C 5H5)]. Deboronation of 1 gives K[7-{Fc}-7,8-nido-C2B9H11] 2, and subsequent metallation, using the {Ru(p-cym)} fragment, affords the novel ferroceny...
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| Format: | Journal article |
| Language: | English |
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1998
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| _version_ | 1826263065972178944 |
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| author | Beckering, C Rosair, G Weller, A |
| author_facet | Beckering, C Rosair, G Weller, A |
| author_sort | Beckering, C |
| collection | OXFORD |
| description | The reaction between ethynyl ferrocene and decaborane affords the new ferrocenyl substituted carborane 1-{Fc}-1,2-closo-C2B10H11 1 [Fc=(η5-C5H4)Fe(η5-C 5H5)]. Deboronation of 1 gives K[7-{Fc}-7,8-nido-C2B9H11] 2, and subsequent metallation, using the {Ru(p-cym)} fragment, affords the novel ferrocenyl substituted ruthenacarborane 1-{Fc}-3-(p-cym)-3,1,2-closo-RuC2B9H10 3 (p-cym=1-Me-C4H4-4-iPr). Reaction between bis(methylethynyl)ferrocene and decaborane affords the bis carborane substituted ferrocene 1,1′-{Fc′}-{2-Me-1,2-closo-C2B10H 10}2, 4 [Fc′=(η5-C5H4)Fe(η 5-C5H4)]. Deboronation of 4 results in the formation [HNMe3]2[7,7′-{Fc′}-{7-Me-7,8-nido-C 2B9H10}2], 5, isolated as a syn and anti diastereoisomeric pair. Metallation of 5 affords the trimetallic ruthenacarborane 1,1-{Fc′}-{2-Me-3-(p-cym)-3,1,2-closo-RuC2B9H 9}2 3, as a mixture of syn and anti diastereoisomers. All the new complexes have been fully characterised by multinuclear NMR and micro-analysis, and for compounds 1, 3, 4 and anti-6 by a single crystal X-ray study. |
| first_indexed | 2024-03-06T19:45:46Z |
| format | Journal article |
| id | oxford-uuid:223fa477-9824-4fe4-987d-1ad13303869f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:45:46Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:223fa477-9824-4fe4-987d-1ad13303869f2022-03-26T11:37:45ZFerrocenyl substituted carboranes: synthesis and characterisationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:223fa477-9824-4fe4-987d-1ad13303869fEnglishSymplectic Elements at Oxford1998Beckering, CRosair, GWeller, AThe reaction between ethynyl ferrocene and decaborane affords the new ferrocenyl substituted carborane 1-{Fc}-1,2-closo-C2B10H11 1 [Fc=(η5-C5H4)Fe(η5-C 5H5)]. Deboronation of 1 gives K[7-{Fc}-7,8-nido-C2B9H11] 2, and subsequent metallation, using the {Ru(p-cym)} fragment, affords the novel ferrocenyl substituted ruthenacarborane 1-{Fc}-3-(p-cym)-3,1,2-closo-RuC2B9H10 3 (p-cym=1-Me-C4H4-4-iPr). Reaction between bis(methylethynyl)ferrocene and decaborane affords the bis carborane substituted ferrocene 1,1′-{Fc′}-{2-Me-1,2-closo-C2B10H 10}2, 4 [Fc′=(η5-C5H4)Fe(η 5-C5H4)]. Deboronation of 4 results in the formation [HNMe3]2[7,7′-{Fc′}-{7-Me-7,8-nido-C 2B9H10}2], 5, isolated as a syn and anti diastereoisomeric pair. Metallation of 5 affords the trimetallic ruthenacarborane 1,1-{Fc′}-{2-Me-3-(p-cym)-3,1,2-closo-RuC2B9H 9}2 3, as a mixture of syn and anti diastereoisomers. All the new complexes have been fully characterised by multinuclear NMR and micro-analysis, and for compounds 1, 3, 4 and anti-6 by a single crystal X-ray study. |
| spellingShingle | Beckering, C Rosair, G Weller, A Ferrocenyl substituted carboranes: synthesis and characterisation |
| title | Ferrocenyl substituted carboranes: synthesis and characterisation |
| title_full | Ferrocenyl substituted carboranes: synthesis and characterisation |
| title_fullStr | Ferrocenyl substituted carboranes: synthesis and characterisation |
| title_full_unstemmed | Ferrocenyl substituted carboranes: synthesis and characterisation |
| title_short | Ferrocenyl substituted carboranes: synthesis and characterisation |
| title_sort | ferrocenyl substituted carboranes synthesis and characterisation |
| work_keys_str_mv | AT beckeringc ferrocenylsubstitutedcarboranessynthesisandcharacterisation AT rosairg ferrocenylsubstitutedcarboranessynthesisandcharacterisation AT wellera ferrocenylsubstitutedcarboranessynthesisandcharacterisation |