A cascade strategy enables a total synthesis of (-)-gephyrotoxin.

A cascade strategy enables a total synthesis of (-)-gephyrotoxin.

A concise and efficient synthesis of (-)-gephyrotoxin from L-pyroglutaminol has been realized. The key step in this approach is a diastereoselective intramolecular enamine/Michael cascade reaction that forms two rings and two stereocenters and generates a stable tricyclic iminium cation. A hydroxy-d...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Chu, S, Wallace, S, Smith, M
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	Wiley 2014

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