The cyclic and linear sweep voltammetry of regular and random arrays of microdisc electrodes: Theory
Microdisc electrode arrays are popular tools in electroanalytical chemistry. In linear sweep and cyclic voltammetry experiments, for optimum performance the individual discs in the array must have a centre-to-centre separation large enough to avoid diffusion zone overlap (which is also known as &quo...
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2005
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| 总结: | Microdisc electrode arrays are popular tools in electroanalytical chemistry. In linear sweep and cyclic voltammetry experiments, for optimum performance the individual discs in the array must have a centre-to-centre separation large enough to avoid diffusion zone overlap (which is also known as "shielding"), but not too large as to result in a waste of surface area. Using a 2-dimensional simulation method, this work examines in detail the currently accepted guidelines on centre-to-centre separation and identifies the key factors involved in the voltammetry of both regular and random arrays of microdisc (and nanodisc) electrodes. © 2005 Elsevier B.V. All rights reserved. |
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