Competing radical and non-radical pathways for the decomposition of LFeII(H2O2) complexes: a density functional study
Density functional theory has been used to explore the mechanism of hydrogen peroxide decomposition when coordinated to a bispidone iron(II) complex. Two quite distinct pathways are identified, one involving O-O bond homolysis followed by a "rebound" hydrogen atom abstraction, the other in...
| Hoofdauteurs: | , , , , |
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| Formaat: | Journal article |
| Taal: | English |
| Gepubliceerd in: |
2007
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