Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad
Paramagnetic endohedral fullerenes and phthalocyanine (Pc) complexes are promising building blocks for molecular quantum information processing, for which tunable dipolar coupling is required. We have linked these two spin qubit candidates together and characterized the resulting electron paramagnet...
| Main Authors: | , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
American Chemical Society
2016
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| _version_ | 1826263587923951616 |
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| author | Zhou, S Yamamoto, M Briggs, G Imahori, H Porfyrakis, K |
| author_facet | Zhou, S Yamamoto, M Briggs, G Imahori, H Porfyrakis, K |
| author_sort | Zhou, S |
| collection | OXFORD |
| description | Paramagnetic endohedral fullerenes and phthalocyanine (Pc) complexes are promising building blocks for molecular quantum information processing, for which tunable dipolar coupling is required. We have linked these two spin qubit candidates together and characterized the resulting electron paramagnetic resonance properties, including the spin dipolar coupling between the fullerene spin and the copper spin. Having interpreted the distance-dependent coupling strength quantitatively and further discussed the antiferromagnetic aggregation effect of the CuPc moieties, we demonstrate two ways of tuning the dipolar coupling in such dyad systems: changing the spacer group and adjusting the solution concentration. |
| first_indexed | 2024-03-06T19:54:11Z |
| format | Journal article |
| id | oxford-uuid:24f9ef38-0dd5-4b2b-8ed5-a0c72df02cf3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:54:11Z |
| publishDate | 2016 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:24f9ef38-0dd5-4b2b-8ed5-a0c72df02cf32022-03-26T11:53:14ZProbing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyadJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:24f9ef38-0dd5-4b2b-8ed5-a0c72df02cf3EnglishSymplectic Elements at OxfordAmerican Chemical Society2016Zhou, SYamamoto, MBriggs, GImahori, HPorfyrakis, KParamagnetic endohedral fullerenes and phthalocyanine (Pc) complexes are promising building blocks for molecular quantum information processing, for which tunable dipolar coupling is required. We have linked these two spin qubit candidates together and characterized the resulting electron paramagnetic resonance properties, including the spin dipolar coupling between the fullerene spin and the copper spin. Having interpreted the distance-dependent coupling strength quantitatively and further discussed the antiferromagnetic aggregation effect of the CuPc moieties, we demonstrate two ways of tuning the dipolar coupling in such dyad systems: changing the spacer group and adjusting the solution concentration. |
| spellingShingle | Zhou, S Yamamoto, M Briggs, G Imahori, H Porfyrakis, K Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title | Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title_full | Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title_fullStr | Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title_full_unstemmed | Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title_short | Probing the dipolar coupling in a heterospin endohedral fullerene-phthalocyanine dyad |
| title_sort | probing the dipolar coupling in a heterospin endohedral fullerene phthalocyanine dyad |
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