Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5]+.
The cationic cages nido-[C2Bu(t)2P2E]+ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.
Bibliographic Details
| Main Authors: |
Fish, C,
Green, M,
Jeffery, J,
Kilby, R,
Lynam, J,
McGrady, J,
Pantazis, D,
Russell, C,
Willans, C |
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| Format: | Journal article
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| Language: | English |
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| Published: |
2006
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