High resolution infrared spectroscopy and structure of CO-N2O
The infrared spectrum of the van der Waals complex CO-N2O has been recorded in the region of the ν3 N2O monomer vibrational band using a diode laser absorption spectrometer which incorporates a multipass cell and a pulsed jet. The spectrum has been completely analyzed using a normal asymmetric rotor...
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| Format: | Journal article |
| Language: | English |
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1997
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| _version_ | 1797058730984996864 |
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| author | Qian, H Howard, B |
| author_facet | Qian, H Howard, B |
| author_sort | Qian, H |
| collection | OXFORD |
| description | The infrared spectrum of the van der Waals complex CO-N2O has been recorded in the region of the ν3 N2O monomer vibrational band using a diode laser absorption spectrometer which incorporates a multipass cell and a pulsed jet. The spectrum has been completely analyzed using a normal asymmetric rotor Hamiltonian and the effective molecular constants are accurately determined for both ground and excited vibrational states. The band origin of CO-N2O is observed to shift toward higher wavenumber from the N2O monomer by 2.90540 cm-1. With the aid of an intermolecular potential calculation, we are able to determine that the complex has a T-shaped configuration with the CO forming the leg of the T and the C atom of the CO molecule pointing to N2O. The structural parameters are R″cm = 3.8707(3) Å, θN2O = 80° ± 5°, and θCO = 20° ± 5°. © 1997 Academic Press. |
| first_indexed | 2024-03-06T19:54:27Z |
| format | Journal article |
| id | oxford-uuid:2512b8b4-4619-4911-bbb9-28ff6ce14245 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:54:27Z |
| publishDate | 1997 |
| record_format | dspace |
| spelling | oxford-uuid:2512b8b4-4619-4911-bbb9-28ff6ce142452022-03-26T11:53:45ZHigh resolution infrared spectroscopy and structure of CO-N2OJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2512b8b4-4619-4911-bbb9-28ff6ce14245EnglishSymplectic Elements at Oxford1997Qian, HHoward, BThe infrared spectrum of the van der Waals complex CO-N2O has been recorded in the region of the ν3 N2O monomer vibrational band using a diode laser absorption spectrometer which incorporates a multipass cell and a pulsed jet. The spectrum has been completely analyzed using a normal asymmetric rotor Hamiltonian and the effective molecular constants are accurately determined for both ground and excited vibrational states. The band origin of CO-N2O is observed to shift toward higher wavenumber from the N2O monomer by 2.90540 cm-1. With the aid of an intermolecular potential calculation, we are able to determine that the complex has a T-shaped configuration with the CO forming the leg of the T and the C atom of the CO molecule pointing to N2O. The structural parameters are R″cm = 3.8707(3) Å, θN2O = 80° ± 5°, and θCO = 20° ± 5°. © 1997 Academic Press. |
| spellingShingle | Qian, H Howard, B High resolution infrared spectroscopy and structure of CO-N2O |
| title | High resolution infrared spectroscopy and structure of CO-N2O |
| title_full | High resolution infrared spectroscopy and structure of CO-N2O |
| title_fullStr | High resolution infrared spectroscopy and structure of CO-N2O |
| title_full_unstemmed | High resolution infrared spectroscopy and structure of CO-N2O |
| title_short | High resolution infrared spectroscopy and structure of CO-N2O |
| title_sort | high resolution infrared spectroscopy and structure of co n2o |
| work_keys_str_mv | AT qianh highresolutioninfraredspectroscopyandstructureofcon2o AT howardb highresolutioninfraredspectroscopyandstructureofcon2o |