Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.
We report theoretical studies into the remote 1,5-stereoinduction shown by certain types of beta-alkoxy methyl ketones in boron-mediated aldol reactions with achiral aldehydes. For a range of common alkoxy groups, our calculations are in excellent agreement with experimentally observed diastereosele...
Olles dieđut
Bibliográfalaš dieđut
Váldodahkkit: |
Paton, R,
Goodman, J |
Materiálatiipa: | Journal article
|
Giella: | English |
Almmustuhtton: |
2006
|