Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.

Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.

We report theoretical studies into the remote 1,5-stereoinduction shown by certain types of beta-alkoxy methyl ketones in boron-mediated aldol reactions with achiral aldehydes. For a range of common alkoxy groups, our calculations are in excellent agreement with experimentally observed diastereosele...

書誌詳細
主要な著者:	Paton, R, Goodman, J
フォーマット:	Journal article
言語:	English
出版事項:	2006

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