Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.

Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.

We report theoretical studies into the remote 1,5-stereoinduction shown by certain types of beta-alkoxy methyl ketones in boron-mediated aldol reactions with achiral aldehydes. For a range of common alkoxy groups, our calculations are in excellent agreement with experimentally observed diastereosele...

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Chi tiết về thư mục
Những tác giả chính:	Paton, R, Goodman, J
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2006

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