Time-resolved in situ diffraction reveals a solid-state rearrangement during solvothermal MOF synthesis
Time-resolved, in situ high energy angular dispersive X-ray powder diffraction (ADXRD) of the hydrothermal synthesis of (H2NMe2)2[Co3(BDC)4]·yDMF proceeds via a topotactic rearrangement in which a structurally-related metastable precursor evolves into the final product via the inter-layer reordering...
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| Médium: | Journal article |
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American Chemical Society
2015
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