REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES
A series of cyclic polyethers, which incorporate the redox active {Mo(NO)}3+ moiety, have been prepared and characterised. The electrochemistry of these complexes has been investigated and their reduction potentials found to undergo anodic shifts upon the binding of alkali metal cations to the cycli...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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Kluwer Academic Publishers
1987
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| _version_ | 1826263845804441600 |
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| author | Beer, P Jones, C Mccleverty, J Salam, S |
| author_facet | Beer, P Jones, C Mccleverty, J Salam, S |
| author_sort | Beer, P |
| collection | OXFORD |
| description | A series of cyclic polyethers, which incorporate the redox active {Mo(NO)}3+ moiety, have been prepared and characterised. The electrochemistry of these complexes has been investigated and their reduction potentials found to undergo anodic shifts upon the binding of alkali metal cations to the cyclic polyether moiety. The magnitude of the shift appears relatively insensitive to the size of the cyclic polyether ring, but is substantially reduced when K+ is used in place of Na+. © 1987 D. Reidel Publishing Company. |
| first_indexed | 2024-03-06T19:58:21Z |
| format | Journal article |
| id | oxford-uuid:266bf533-1ce5-4a5b-a202-49c3195613ff |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:58:21Z |
| publishDate | 1987 |
| publisher | Kluwer Academic Publishers |
| record_format | dspace |
| spelling | oxford-uuid:266bf533-1ce5-4a5b-a202-49c3195613ff2022-03-26T12:00:49ZREDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:266bf533-1ce5-4a5b-a202-49c3195613ffEnglishSymplectic Elements at OxfordKluwer Academic Publishers1987Beer, PJones, CMccleverty, JSalam, SA series of cyclic polyethers, which incorporate the redox active {Mo(NO)}3+ moiety, have been prepared and characterised. The electrochemistry of these complexes has been investigated and their reduction potentials found to undergo anodic shifts upon the binding of alkali metal cations to the cyclic polyether moiety. The magnitude of the shift appears relatively insensitive to the size of the cyclic polyether ring, but is substantially reduced when K+ is used in place of Na+. © 1987 D. Reidel Publishing Company. |
| spellingShingle | Beer, P Jones, C Mccleverty, J Salam, S REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title | REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title_full | REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title_fullStr | REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title_full_unstemmed | REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title_short | REDOX RESPONSIVE METAL-COMPLEXES CONTAINING CATION BINDING-SITES |
| title_sort | redox responsive metal complexes containing cation binding sites |
| work_keys_str_mv | AT beerp redoxresponsivemetalcomplexescontainingcationbindingsites AT jonesc redoxresponsivemetalcomplexescontainingcationbindingsites AT mcclevertyj redoxresponsivemetalcomplexescontainingcationbindingsites AT salams redoxresponsivemetalcomplexescontainingcationbindingsites |