Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets
Aryl derivatives of ferrocene are used for the modification of graphitic surfaces. Stronger adsorption is utilized as a route to enable the electrochemically tagging of new carbon materials. Model experiments are reported on an EPPG electrode where the adsorption of 1-(biphen-4-yl)ferrocene is found...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Journal article |
| Published: |
Wiley
2016
|
| _version_ | 1797059032220958720 |
|---|---|
| author | Yang, M Batchelor-McAuley, C Moreira Goncalves, L Lima, C Vyskocil, V Tschulik, K Compton, R |
| author_facet | Yang, M Batchelor-McAuley, C Moreira Goncalves, L Lima, C Vyskocil, V Tschulik, K Compton, R |
| author_sort | Yang, M |
| collection | OXFORD |
| description | Aryl derivatives of ferrocene are used for the modification of graphitic surfaces. Stronger adsorption is utilized as a route to enable the electrochemically tagging of new carbon materials. Model experiments are reported on an EPPG electrode where the adsorption of 1-(biphen-4-yl)ferrocene is found to be a factor of ca. 5 times more thermodynamically favorable than the underivatised form. Two further derivatives were also studied and the voltammetric responses of this class of ferrocenes are found to be significantly influenced by ion-pairing. Finally, the successful use of these new materials for the modification and redox tagging of graphene nanoplatelets is demonstrated. © 2016 WILEY-VCH Verlag GmbH and Co. |
| first_indexed | 2024-03-06T19:58:30Z |
| format | Journal article |
| id | oxford-uuid:2676ff8b-cd44-4a6b-913e-7e0c6dbb3ecd |
| institution | University of Oxford |
| last_indexed | 2024-03-06T19:58:30Z |
| publishDate | 2016 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:2676ff8b-cd44-4a6b-913e-7e0c6dbb3ecd2022-03-26T12:01:07ZFerrocene aryl derivatives for the redox tagging of graphene nanoplateletsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2676ff8b-cd44-4a6b-913e-7e0c6dbb3ecdSymplectic Elements at OxfordWiley2016Yang, MBatchelor-McAuley, CMoreira Goncalves, LLima, CVyskocil, VTschulik, KCompton, RAryl derivatives of ferrocene are used for the modification of graphitic surfaces. Stronger adsorption is utilized as a route to enable the electrochemically tagging of new carbon materials. Model experiments are reported on an EPPG electrode where the adsorption of 1-(biphen-4-yl)ferrocene is found to be a factor of ca. 5 times more thermodynamically favorable than the underivatised form. Two further derivatives were also studied and the voltammetric responses of this class of ferrocenes are found to be significantly influenced by ion-pairing. Finally, the successful use of these new materials for the modification and redox tagging of graphene nanoplatelets is demonstrated. © 2016 WILEY-VCH Verlag GmbH and Co. |
| spellingShingle | Yang, M Batchelor-McAuley, C Moreira Goncalves, L Lima, C Vyskocil, V Tschulik, K Compton, R Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title | Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title_full | Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title_fullStr | Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title_full_unstemmed | Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title_short | Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| title_sort | ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets |
| work_keys_str_mv | AT yangm ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT batchelormcauleyc ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT moreiragoncalvesl ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT limac ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT vyskocilv ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT tschulikk ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets AT comptonr ferrocenearylderivativesfortheredoxtaggingofgraphenenanoplatelets |