Structural diversity in organically templated uranium sulfates
The potential of organic amine templates to direct the synthesis of metal sulfate frameworks has been investigated. Eight novel uranyl sulfates have been prepared using a templated uranyl sulfate precursor under hydrothermal conditions. The topologis of the isolated phases vary from the molecular (0...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2003
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| 总结: | The potential of organic amine templates to direct the synthesis of metal sulfate frameworks has been investigated. Eight novel uranyl sulfates have been prepared using a templated uranyl sulfate precursor under hydrothermal conditions. The topologis of the isolated phases vary from the molecular (0-D), to chains (1-D) to layered (2-D) frameworks. [N4C6H 22]2[(UO2)2(SO4) 6] (USO-10) is molecular or zero-dimensional. Two different types of onedimensional uranyl-containing chains have been observed. [N2C 4H12][UO2(H2O)(SO4) 2 (USO-3), [N2C5H14]-[UO 2(H2O)(SO4)2] (USO-4) and [N 2C3H12][UO2(H2O)(SO 4)2 (USO-9) contain chains based upon a [UO 2(SO4)4/2] backbone. [N2C 10H10][UO2(SO4)2· H2O (USO-6) and [N2C6H18][(UO 2)2(H2O)3(SO4) 3] (USO-7) contain chains based upon a [UO2(SO 4)3/3] backbone. Two layered or two-dimensional compounds, [N2C6H14][UO2(H2O) (SO4)2 (USO-5) and [N2C3H 5]2[(UO2)2(SO4) 3] (USO-8) have also been isolated. All the new phases have been characterised using a range of physical techniques including single crystal X-ray structure analysis. © The Royal Society of Chemistry 2003. |
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