Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3)
Reaction of the diamidopyridine protio-ligand MeC(2-C5H 4N){CH2N(H)Mes}2 (Mes = 2,4,6-C 6H2Me3) with butyllithium in diethyl ether affords the compound (diethyl ether)(μ4-2-{6-[1,3-dimethyl-3-(2- pyridyl)-1,4-bis(2,4,6-trimethylanilinio)butyl]-2-pyridyl}-2-methyl-1,3-bis(2,4, 6-trimethylanilinio)pro...
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| Format: | Journal article |
| Language: | English |
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2006
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| _version_ | 1797059246891728896 |
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| author | Ward, B Gade, L Mountford, P |
| author_facet | Ward, B Gade, L Mountford, P |
| author_sort | Ward, B |
| collection | OXFORD |
| description | Reaction of the diamidopyridine protio-ligand MeC(2-C5H 4N){CH2N(H)Mes}2 (Mes = 2,4,6-C 6H2Me3) with butyllithium in diethyl ether affords the compound (diethyl ether)(μ4-2-{6-[1,3-dimethyl-3-(2- pyridyl)-1,4-bis(2,4,6-trimethylanilinio)butyl]-2-pyridyl}-2-methyl-1,3-bis(2,4, 6-trimethylanilinio)propane)tetralithium(I), [Li4(C 55H64N6)(C4 H10O)] or Li4[MeC(2-C5H4N){CH2N(Mes)}CHN(2,4, 6-C6H2-Me2C(Me)(2,2′-C5H 3N){C(Me)}(CH2NMes)2](OEt2), which shows the methylation of the pyridyl ortho-position with a methyl group of one of the mesityl groups. The complex contains four Li atoms, each of which is chemically distinct. The tetraanionic ligand contains two protio-ligand units which are fused together into a single entity. The structure contains two disordered molecules of diethyl ether, one of which is coordinated to one of the Li atoms. © 2006 International Union of Crystallography All rights reserved. |
| first_indexed | 2024-03-06T20:01:27Z |
| format | Journal article |
| id | oxford-uuid:2770c78b-bc1b-4acd-9f8b-19ae306e2e30 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:01:27Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:2770c78b-bc1b-4acd-9f8b-19ae306e2e302022-03-26T12:06:58ZLithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2770c78b-bc1b-4acd-9f8b-19ae306e2e30EnglishSymplectic Elements at Oxford2006Ward, BGade, LMountford, PReaction of the diamidopyridine protio-ligand MeC(2-C5H 4N){CH2N(H)Mes}2 (Mes = 2,4,6-C 6H2Me3) with butyllithium in diethyl ether affords the compound (diethyl ether)(μ4-2-{6-[1,3-dimethyl-3-(2- pyridyl)-1,4-bis(2,4,6-trimethylanilinio)butyl]-2-pyridyl}-2-methyl-1,3-bis(2,4, 6-trimethylanilinio)propane)tetralithium(I), [Li4(C 55H64N6)(C4 H10O)] or Li4[MeC(2-C5H4N){CH2N(Mes)}CHN(2,4, 6-C6H2-Me2C(Me)(2,2′-C5H 3N){C(Me)}(CH2NMes)2](OEt2), which shows the methylation of the pyridyl ortho-position with a methyl group of one of the mesityl groups. The complex contains four Li atoms, each of which is chemically distinct. The tetraanionic ligand contains two protio-ligand units which are fused together into a single entity. The structure contains two disordered molecules of diethyl ether, one of which is coordinated to one of the Li atoms. © 2006 International Union of Crystallography All rights reserved. |
| spellingShingle | Ward, B Gade, L Mountford, P Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title | Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title_full | Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title_fullStr | Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title_full_unstemmed | Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title_short | Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}(2) (Mes=2,4,6-C6H2Me3) |
| title_sort | lithiation of the diaminopyridine protio ligand mec 2 c5h4n ch2n h mes 2 mes 2 4 6 c6h2me3 |
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