Coupling strategies to enhance single-molecule magnet properties of erbium-cyclooctatetraenyl complexes

Two different coupling strategies were employed to create ErIII single-molecule magnets (SMMs) using high blocking temperature mononuclear precursors. The magnetic properties of three lanthanide–COT complexes, [ErIII2(COT′′)3] (1) (COT′′ = 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion) and K2(TH...

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Bibliographic Details
Main Authors: le Roy, J, Ungur, L, Korobkov, I, Chibotaru, L, Murugesu, M
Format: Journal article
Published: American Chemical Society 2014