Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand

© 2016 Springer-Verlag Berlin Heidelberg The world-class Macraes orogenic gold deposit (∼10 Moz resource) formed during the late metamorphic uplift of a metasedimentary schist belt in southern New Zealand. Mineralising fluids, metals and metalloids were derived from within the metasedimentary host....

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Váldodahkkit: Goodwin, N, Burgess, R, Craw, D, Teagle, D, Ballentine, C
Materiálatiipa: Journal article
Almmustuhtton: Springer Berlin Heidelberg 2016
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author Goodwin, N
Burgess, R
Craw, D
Teagle, D
Ballentine, C
author_facet Goodwin, N
Burgess, R
Craw, D
Teagle, D
Ballentine, C
author_sort Goodwin, N
collection OXFORD
description © 2016 Springer-Verlag Berlin Heidelberg The world-class Macraes orogenic gold deposit (∼10 Moz resource) formed during the late metamorphic uplift of a metasedimentary schist belt in southern New Zealand. Mineralising fluids, metals and metalloids were derived from within the metasedimentary host. Helium and argon extracted from fluid inclusions in sulphide mineral grains (three crush extractions from one sample) have crustal signatures, with no evidence for mantle input (R/Ra = 0.03). Xenon extracted from mineralised quartz samples provides evidence for extensive interaction between fluid and maturing organic material within the metasedimentary host rocks, with 132Xe/36Ar ratios up to 200 times greater than air. Similarly, I/Cl ratios for fluids extracted from mineralised quartz are similar to those of brines from marine sediments that have interacted with organic matter and are ten times higher than typical magmatic/mantle fluids. The Macraes mineralising fluids were compositionally variable, reflecting either mixing of two different crustal fluids in the metasedimentary pile or a single fluid type that has had varying degrees of interaction with the host metasediments. Evidence for additional input of meteoric water is equivocal, but minor meteoric incursion cannot be discounted. The Macraes deposit formed in a metasedimentary belt without associated coeval magmatism, and therefore represents a purely crustal metamorphogenic end member in a spectrum of orogenic hydrothermal processes that can include magmatic and/or mantle fluid input elsewhere in the world. There is no evidence for involvement of minor intercalated metabasic rocks in the Macraes mineralising system. Hydrothermal fluids that formed other, smaller, orogenic deposits in the same metamorphic belt have less pronounced noble gas and halogen evidence for crustal fluid-rock interaction than at Macraes, but these deposits also formed from broadly similar metamorphogenic processes.
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spelling oxford-uuid:27cdb59b-013b-4de2-89bd-387aa1f85aef2022-03-26T12:09:06ZNoble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New ZealandJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:27cdb59b-013b-4de2-89bd-387aa1f85aefSymplectic Elements at OxfordSpringer Berlin Heidelberg2016Goodwin, NBurgess, RCraw, DTeagle, DBallentine, C© 2016 Springer-Verlag Berlin Heidelberg The world-class Macraes orogenic gold deposit (∼10 Moz resource) formed during the late metamorphic uplift of a metasedimentary schist belt in southern New Zealand. Mineralising fluids, metals and metalloids were derived from within the metasedimentary host. Helium and argon extracted from fluid inclusions in sulphide mineral grains (three crush extractions from one sample) have crustal signatures, with no evidence for mantle input (R/Ra = 0.03). Xenon extracted from mineralised quartz samples provides evidence for extensive interaction between fluid and maturing organic material within the metasedimentary host rocks, with 132Xe/36Ar ratios up to 200 times greater than air. Similarly, I/Cl ratios for fluids extracted from mineralised quartz are similar to those of brines from marine sediments that have interacted with organic matter and are ten times higher than typical magmatic/mantle fluids. The Macraes mineralising fluids were compositionally variable, reflecting either mixing of two different crustal fluids in the metasedimentary pile or a single fluid type that has had varying degrees of interaction with the host metasediments. Evidence for additional input of meteoric water is equivocal, but minor meteoric incursion cannot be discounted. The Macraes deposit formed in a metasedimentary belt without associated coeval magmatism, and therefore represents a purely crustal metamorphogenic end member in a spectrum of orogenic hydrothermal processes that can include magmatic and/or mantle fluid input elsewhere in the world. There is no evidence for involvement of minor intercalated metabasic rocks in the Macraes mineralising system. Hydrothermal fluids that formed other, smaller, orogenic deposits in the same metamorphic belt have less pronounced noble gas and halogen evidence for crustal fluid-rock interaction than at Macraes, but these deposits also formed from broadly similar metamorphogenic processes.
spellingShingle Goodwin, N
Burgess, R
Craw, D
Teagle, D
Ballentine, C
Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title_full Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title_fullStr Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title_full_unstemmed Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title_short Noble gases fingerprint a metasedimentary fluid source in the Macraes orogenic gold deposit, New Zealand
title_sort noble gases fingerprint a metasedimentary fluid source in the macraes orogenic gold deposit new zealand
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