Electrochemical characterization of sulfide tagging via its reaction with benzoquinone derivatives
The voltammetric response of a range of structurally diverse substituted benzoquinones species (p-benzoquinone, 2,3-dimethoxy-5-methyl-p-benzoquinone, 2,6-dimethoxy-p-benzoquinone, and 3,5-ditert-butyl-o-benzoquinone) to increasing additions of sulfide has been examined using square wave voltammetry...
| Հիմնական հեղինակներ: | , , , , |
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| Ձևաչափ: | Journal article |
| Լեզու: | English |
| Հրապարակվել է: |
2003
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| Ամփոփում: | The voltammetric response of a range of structurally diverse substituted benzoquinones species (p-benzoquinone, 2,3-dimethoxy-5-methyl-p-benzoquinone, 2,6-dimethoxy-p-benzoquinone, and 3,5-ditert-butyl-o-benzoquinone) to increasing additions of sulfide has been examined using square wave voltammetry. In all cases the response shows that the quinone undergoes a reaction with sulfide to form a new redox active species. It is shown that by judicious choice of the pH of the solution analytical signals can be obtained for each species; the corresponding analytical parameters are detailed and the results critically appraised. |
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