THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS
The complexes fac-[PtMe3L]Cl (1: L = 1,4,7-tritiacyclononane; 2: L = 1,4,7,10-tetrathiacyclododecane; or 3: L = 10-oxa-1,4,7-trithiacyclododecane) have been prepared by reaction of L with [{PtClMe3}4] in CDCl3. Variable temperature 1H and 13C{1H} NMR studies have shown that the complex 2 undergoes a...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1988
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| _version_ | 1797059581734551552 |
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| author | Abel, E Beer, P Moss, I Orrell, K Sik, V Bates, P Hursthouse, M |
| author_facet | Abel, E Beer, P Moss, I Orrell, K Sik, V Bates, P Hursthouse, M |
| author_sort | Abel, E |
| collection | OXFORD |
| description | The complexes fac-[PtMe3L]Cl (1: L = 1,4,7-tritiacyclononane; 2: L = 1,4,7,10-tetrathiacyclododecane; or 3: L = 10-oxa-1,4,7-trithiacyclododecane) have been prepared by reaction of L with [{PtClMe3}4] in CDCl3. Variable temperature 1H and 13C{1H} NMR studies have shown that the complex 2 undergoes a novel ligand commutation involving exchange between metal-coordinated and uncoordinated sulphur atoms of the macrocycle. In contrast, 1 and 3 exhibit temperature-invariant NMR spectra. © 1988. |
| first_indexed | 2024-03-06T20:06:22Z |
| format | Journal article |
| id | oxford-uuid:29083ac7-9da4-427f-b2ca-9d230b7e6510 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:06:22Z |
| publishDate | 1988 |
| record_format | dspace |
| spelling | oxford-uuid:29083ac7-9da4-427f-b2ca-9d230b7e65102022-03-26T12:16:41ZTHE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:29083ac7-9da4-427f-b2ca-9d230b7e6510EnglishSymplectic Elements at Oxford1988Abel, EBeer, PMoss, IOrrell, KSik, VBates, PHursthouse, MThe complexes fac-[PtMe3L]Cl (1: L = 1,4,7-tritiacyclononane; 2: L = 1,4,7,10-tetrathiacyclododecane; or 3: L = 10-oxa-1,4,7-trithiacyclododecane) have been prepared by reaction of L with [{PtClMe3}4] in CDCl3. Variable temperature 1H and 13C{1H} NMR studies have shown that the complex 2 undergoes a novel ligand commutation involving exchange between metal-coordinated and uncoordinated sulphur atoms of the macrocycle. In contrast, 1 and 3 exhibit temperature-invariant NMR spectra. © 1988. |
| spellingShingle | Abel, E Beer, P Moss, I Orrell, K Sik, V Bates, P Hursthouse, M THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title | THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title_full | THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title_fullStr | THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title_full_unstemmed | THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title_short | THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS |
| title_sort | preparation and dynamic behavior of platinum iv derivatives of macrocyclic thioethers |
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