THE PREPARATION AND DYNAMIC BEHAVIOR OF PLATINUM(IV) DERIVATIVES OF MACROCYCLIC THIOETHERS
The complexes fac-[PtMe3L]Cl (1: L = 1,4,7-tritiacyclononane; 2: L = 1,4,7,10-tetrathiacyclododecane; or 3: L = 10-oxa-1,4,7-trithiacyclododecane) have been prepared by reaction of L with [{PtClMe3}4] in CDCl3. Variable temperature 1H and 13C{1H} NMR studies have shown that the complex 2 undergoes a...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1988
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