La2SrCr2O7F2: A Ruddlesden–Popper oxyfluoride containing octahedrally coordinated Cr4+ centers

The low-temperature fluorination of the n = 2 Ruddlesden–Popper phase La2SrCr2O7 yields La2SrCr2O7F2 via a topochemical fluorine insertion reaction. The structure-conserving nature of the fluorination reaction means that the chromium centers of the initial oxide phase retain an octahedral coordinati...

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Những tác giả chính: Hayward, M, Blundell, S, Zhang, R, Read, G, Lang, F, Lancaster, T
Định dạng: Journal article
Được phát hành: American Chemical Society 2016