Chiral glycine cation equivalents: N-acyliminium species derived from diketopiperazines
Studies towards a N,N′-bis(p-methoxybenzyl)diketopiperazine asymmetric glycine cation equivalent for the synthesis of homochiral α-amino acids are described. The oxidation of enolate 3 with molecular oxygen provides either a mixture of hydroxylated diketopiperazines 7 and 8 or trione 10 depending up...
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Bibliographic Details
| Main Authors: |
Bull, S,
Davies, S,
Garner, A,
O'Shea, MD,
Savory, E,
Snow, E |
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| Format: | Journal article
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| Language: | English |
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| Published: |
2002
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