Chiral glycine cation equivalents: N-acyliminium species derived from diketopiperazines

Chiral glycine cation equivalents: N-acyliminium species derived from diketopiperazines

Studies towards a N,N′-bis(p-methoxybenzyl)diketopiperazine asymmetric glycine cation equivalent for the synthesis of homochiral α-amino acids are described. The oxidation of enolate 3 with molecular oxygen provides either a mixture of hydroxylated diketopiperazines 7 and 8 or trione 10 depending up...

書誌詳細
主要な著者:	Bull, S, Davies, S, Garner, A, O'Shea, MD, Savory, E, Snow, E
フォーマット:	Journal article
言語:	English
出版事項:	2002

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