CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH
A conceptually simple and computationally efficient implicit approach to the simulation of current/time transients at the channel electrode is presented. The generality of the method is illustrated with reference to the simple case of a step between potentials corresponding to zero and transport-lim...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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1991
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| _version_ | 1826264579023306752 |
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| author | Fisher, A Compton, R |
| author_facet | Fisher, A Compton, R |
| author_sort | Fisher, A |
| collection | OXFORD |
| description | A conceptually simple and computationally efficient implicit approach to the simulation of current/time transients at the channel electrode is presented. The generality of the method is illustrated with reference to the simple case of a step between potentials corresponding to zero and transport-limited currents for a simple redox reaction (where good agreement with existing analytical theory is found), to ECE and to DISP1 processes, and finally to the case of double-potential steps. The latter are confirmed to be a possible means of distinguishing between ECE and DISP1 reactions. © 1991 American Chemical Society. |
| first_indexed | 2024-03-06T20:10:06Z |
| format | Journal article |
| id | oxford-uuid:2a41cd10-64cf-47c0-9d04-9885be7b1b4f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:10:06Z |
| publishDate | 1991 |
| record_format | dspace |
| spelling | oxford-uuid:2a41cd10-64cf-47c0-9d04-9885be7b1b4f2022-03-26T12:24:00ZCHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACHJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2a41cd10-64cf-47c0-9d04-9885be7b1b4fEnglishSymplectic Elements at Oxford1991Fisher, ACompton, RA conceptually simple and computationally efficient implicit approach to the simulation of current/time transients at the channel electrode is presented. The generality of the method is illustrated with reference to the simple case of a step between potentials corresponding to zero and transport-limited currents for a simple redox reaction (where good agreement with existing analytical theory is found), to ECE and to DISP1 processes, and finally to the case of double-potential steps. The latter are confirmed to be a possible means of distinguishing between ECE and DISP1 reactions. © 1991 American Chemical Society. |
| spellingShingle | Fisher, A Compton, R CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title | CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title_full | CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title_fullStr | CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title_full_unstemmed | CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title_short | CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH |
| title_sort | chronoamperometry at channel electrodes a general computational approach |
| work_keys_str_mv | AT fishera chronoamperometryatchannelelectrodesageneralcomputationalapproach AT comptonr chronoamperometryatchannelelectrodesageneralcomputationalapproach |