Reactions of 'GaI' with organometallic transition metal halides

Two approaches towards the synthesis of phosphine ligated half-sandwich complexes [(ηx-CxHx)M(PR3)2GaI2]n containing diiodogallyl ligands have been investigated. Insertion of 'GaI' into the Mo-I bond of (η7-C7H7)Mo(CO)2I has been shown to yield the crystallographically characterized dimeri...

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Main Authors: Coombs, N, Stasch, A, Aldridge, S
格式: Journal article
语言:English
出版: 2008