Asymmetric remote C-H functionalization: use of internal olefins in tandem hydrometallation-isomerization-asymmetric conjugate addition sequences
We describe catalytic asymmetric C-C formation using terminal alkyl-metal nucleophiles generated from internal olefins through a 'chain-walking' isomerization mechanism. Hydrometallation of internal olefins with the Schwartz reagent gives the least hindered alkyl-zirconocene after thermal...
| Príomhchruthaitheoirí: | , , |
|---|---|
| Formáid: | Journal article |
| Foilsithe / Cruthaithe: |
CSIRO Publishing
2015
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Asymmetric remote C-H functionalization: Use of internal olefins in tandem hydrometallation – isomerization – asymmetric conjugate addition sequences
Foilsithe / Cruthaithe 2014
Journal article