Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.

Fully quantum state selected and resolved inelastic scattering of NO(X) by krypton has been investigated. Initial Λ-doublet state selection is achieved using an inhomogeneous hexapole electric field. Differential cross sections and even-moment polarization dependent differential cross sections have...

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Main Authors: Brouard, M, Chadwick, H, Gordon, S, Hornung, B, Nichols, B, Kłos, J, Aoiz, F, Stolte, S
Format: Journal article
Language:English
Published: American Institute of Physics 2014
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author Brouard, M
Chadwick, H
Gordon, S
Hornung, B
Nichols, B
Kłos, J
Aoiz, F
Stolte, S
author_facet Brouard, M
Chadwick, H
Gordon, S
Hornung, B
Nichols, B
Kłos, J
Aoiz, F
Stolte, S
author_sort Brouard, M
collection OXFORD
description Fully quantum state selected and resolved inelastic scattering of NO(X) by krypton has been investigated. Initial Λ-doublet state selection is achieved using an inhomogeneous hexapole electric field. Differential cross sections and even-moment polarization dependent differential cross sections have been obtained at a collision energy of 514 cm^−1 for both spin-orbit and parity conserving and changing collisions. Experimental results are compared with those obtained from quantum scattering calculations and are shown to be in very good agreement. Hard shell quantum scattering calculations are also performed to determine the effects of the different parts of the potential on the scattering dynamics. Comparisons are also made with the NO(X)+Ar system.
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spelling oxford-uuid:2b4af51f-c8e7-415b-bed4-5fdcaab603382022-03-26T12:30:00ZFully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2b4af51f-c8e7-415b-bed4-5fdcaab60338EnglishSymplectic Elements at OxfordAmerican Institute of Physics2014Brouard, MChadwick, HGordon, SHornung, BNichols, BKłos, JAoiz, FStolte, SFully quantum state selected and resolved inelastic scattering of NO(X) by krypton has been investigated. Initial Λ-doublet state selection is achieved using an inhomogeneous hexapole electric field. Differential cross sections and even-moment polarization dependent differential cross sections have been obtained at a collision energy of 514 cm^−1 for both spin-orbit and parity conserving and changing collisions. Experimental results are compared with those obtained from quantum scattering calculations and are shown to be in very good agreement. Hard shell quantum scattering calculations are also performed to determine the effects of the different parts of the potential on the scattering dynamics. Comparisons are also made with the NO(X)+Ar system.
spellingShingle Brouard, M
Chadwick, H
Gordon, S
Hornung, B
Nichols, B
Kłos, J
Aoiz, F
Stolte, S
Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title_full Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title_fullStr Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title_full_unstemmed Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title_short Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.
title_sort fully quantum state resolved inelastic scattering of no x kr differential cross sections and product rotational alignment
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AT chadwickh fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment
AT gordons fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment
AT hornungb fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment
AT nicholsb fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment
AT kłosj fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment
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AT stoltes fullyquantumstateresolvedinelasticscatteringofnoxkrdifferentialcrosssectionsandproductrotationalalignment