Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst

A range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved.

Bibliographic Details
Main Authors: Hodgson, D, Angrish, D
Format: Conference item
Published: 2006
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author Hodgson, D
Angrish, D
author_facet Hodgson, D
Angrish, D
author_sort Hodgson, D
collection OXFORD
description A range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved.
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spelling oxford-uuid:2b84203a-8533-4671-9f28-cbed888f0e5a2022-03-26T12:31:23ZUnsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalystConference itemhttp://purl.org/coar/resource_type/c_5794uuid:2b84203a-8533-4671-9f28-cbed888f0e5aSymplectic Elements at Oxford2006Hodgson, DAngrish, DA range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved.
spellingShingle Hodgson, D
Angrish, D
Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title_full Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title_fullStr Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title_full_unstemmed Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title_short Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
title_sort unsymmetrical maleates from stereoselective decomposition of diazoesters using grubbs 2nd generation ru carbene catalyst
work_keys_str_mv AT hodgsond unsymmetricalmaleatesfromstereoselectivedecompositionofdiazoestersusinggrubbs2ndgenerationrucarbenecatalyst
AT angrishd unsymmetricalmaleatesfromstereoselectivedecompositionofdiazoestersusinggrubbs2ndgenerationrucarbenecatalyst