Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
A range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved.
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2006
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author | Hodgson, D Angrish, D |
author_facet | Hodgson, D Angrish, D |
author_sort | Hodgson, D |
collection | OXFORD |
description | A range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved. |
first_indexed | 2024-03-06T20:13:57Z |
format | Conference item |
id | oxford-uuid:2b84203a-8533-4671-9f28-cbed888f0e5a |
institution | University of Oxford |
last_indexed | 2024-03-06T20:13:57Z |
publishDate | 2006 |
record_format | dspace |
spelling | oxford-uuid:2b84203a-8533-4671-9f28-cbed888f0e5a2022-03-26T12:31:23ZUnsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalystConference itemhttp://purl.org/coar/resource_type/c_5794uuid:2b84203a-8533-4671-9f28-cbed888f0e5aSymplectic Elements at Oxford2006Hodgson, DAngrish, DA range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved. |
spellingShingle | Hodgson, D Angrish, D Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title | Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title_full | Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title_fullStr | Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title_full_unstemmed | Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title_short | Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst |
title_sort | unsymmetrical maleates from stereoselective decomposition of diazoesters using grubbs 2nd generation ru carbene catalyst |
work_keys_str_mv | AT hodgsond unsymmetricalmaleatesfromstereoselectivedecompositionofdiazoestersusinggrubbs2ndgenerationrucarbenecatalyst AT angrishd unsymmetricalmaleatesfromstereoselectivedecompositionofdiazoestersusinggrubbs2ndgenerationrucarbenecatalyst |