Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs' 2nd-generation Ru carbene catalyst
A range of unsymmetrical cis-2-ene-1,4-diesters has been synthesized from two different α-diazoacetates using Grubbs' 2nd-generation catalyst (0.5 mol%, RT, 12-16 h). Formation of the enediesters occurred with high stereoselectivity (≥95% cis). © 2006 Elsevier B.V. All rights reserved.
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| Format: | Conference item |
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2006
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