Oxasilacyclopentanes as intermediates for silicon tethered ene cyclisations

Oxasilacyclopentanes 3, generated by either free-radical cyclisation, intramolecular hydrosilylation, or silicon tethered Diels-Alder reaction, may be efficiently opened with 2-propenyl-lithium and the product alcohols oxidised to prepare precursors 2 for silicon tethered ene cyclisation. Efficient...

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Bibliografiska uppgifter
Huvudupphovsmän: Robertson, J, Middleton, D, O'Connor, G, Sardharwala, T
Materialtyp: Journal article
Språk:English
Publicerad: 1998