MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES
Velocity-aligned, superthermal atoms generated via polarised molecular photodissociation have been used to investigate vector correlations of bimolecular reactions. Doppler-resolved, polarised laser-probe techniques can measure correlations between k (the reagents' relative-velocity vectors), k...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
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1991
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| _version_ | 1826265112861736960 |
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| author | Green, F Hancock, G Orrewing, A Brouard, M Duxon, S Enriquez, P Sayos, R Simons, J |
| author_facet | Green, F Hancock, G Orrewing, A Brouard, M Duxon, S Enriquez, P Sayos, R Simons, J |
| author_sort | Green, F |
| collection | OXFORD |
| description | Velocity-aligned, superthermal atoms generated via polarised molecular photodissociation have been used to investigate vector correlations of bimolecular reactions. Doppler-resolved, polarised laser-probe techniques can measure correlations between k (the reagents' relative-velocity vectors), k′ (the reaction products' velocity vectors) and J′ (the products' rotational angular momenta using a simple laboratory to centre-of-mass frame transformation. This approach to the study of the dynamical stereo-chemistry of chemical reactions is illustrated by two examples, O(1D)+N2O→NO+NO and O(3P)+CS→CO+S. © 1991. |
| first_indexed | 2024-03-06T20:18:35Z |
| format | Journal article |
| id | oxford-uuid:2d0275d7-4b1a-46b2-a296-2e12c12566b6 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T20:18:35Z |
| publishDate | 1991 |
| record_format | dspace |
| spelling | oxford-uuid:2d0275d7-4b1a-46b2-a296-2e12c12566b62022-03-26T12:40:17ZMEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2d0275d7-4b1a-46b2-a296-2e12c12566b6Symplectic Elements at Oxford1991Green, FHancock, GOrrewing, ABrouard, MDuxon, SEnriquez, PSayos, RSimons, JVelocity-aligned, superthermal atoms generated via polarised molecular photodissociation have been used to investigate vector correlations of bimolecular reactions. Doppler-resolved, polarised laser-probe techniques can measure correlations between k (the reagents' relative-velocity vectors), k′ (the reaction products' velocity vectors) and J′ (the products' rotational angular momenta using a simple laboratory to centre-of-mass frame transformation. This approach to the study of the dynamical stereo-chemistry of chemical reactions is illustrated by two examples, O(1D)+N2O→NO+NO and O(3P)+CS→CO+S. © 1991. |
| spellingShingle | Green, F Hancock, G Orrewing, A Brouard, M Duxon, S Enriquez, P Sayos, R Simons, J MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title | MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title_full | MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title_fullStr | MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title_full_unstemmed | MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title_short | MEASUREMENTS OF VECTOR CORRELATIONS IN BIOMOLECULAR REACTIONS BY LASER-PUMP AND PROBE TECHNIQUES |
| title_sort | measurements of vector correlations in biomolecular reactions by laser pump and probe techniques |
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