Cross-conjugation increases the conductance of meta-connected fluorenones.
<p>Charge transport is strongly suppressed by destructive quantum interference (DQI) in <em>meta</em>-connected 1,1′-biphenyl-containing molecules, resulting in low electrical conductance. Surprisingly, we have found that DQI is almost entirely overcome by adding a bridging carbony...
| Auteurs principaux: | , , , , , , , , , , , , , |
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| Format: | Journal article |
| Langue: | English |
| Publié: |
Royal Society of Chemistry
2019
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| Résumé: | <p>Charge transport is strongly suppressed by destructive quantum interference (DQI) in <em>meta</em>-connected 1,1′-biphenyl-containing molecules, resulting in low electrical conductance. Surprisingly, we have found that DQI is almost entirely overcome by adding a bridging carbonyl, to yield a cross-conjugated fluorenone. This contrasts with other π-systems, such as <em>para</em>-connected anthraquinone, where cross-conjugation results in low conductance.</p> |
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