From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions.
The controlled chemical activation of white phosphorus is a versatile, albeit often unpredictable, route to phosphorus containing species of varied nuclearities. The product distribution is particularly dependent on stoichiometry, temperature, and solvent. Low boiling point, highly polar solvents su...
| Hlavní autoři: | , |
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| Médium: | Journal article |
| Jazyk: | English |
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American Chemical Society
2014
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| _version_ | 1826265209150373888 |
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| author | Turbervill, R Goicoechea, J |
| author_facet | Turbervill, R Goicoechea, J |
| author_sort | Turbervill, R |
| collection | OXFORD |
| description | The controlled chemical activation of white phosphorus is a versatile, albeit often unpredictable, route to phosphorus containing species of varied nuclearities. The product distribution is particularly dependent on stoichiometry, temperature, and solvent. Low boiling point, highly polar solvents such as ammonia tend to favor formation of relatively small polyphosphides, whereas higher boiling or less polar solvents tend to favor formation of more highly aggregated anions. Binary solids and molecular anions are inextricably linked by both shared structural motifs and indeed the ability to extract solvated anions from the solid phases themselves. The chemistry of the polyarsenide, polystibide, and polybismuthide analogues is substantially less well developed, no doubt due to the lack of a suitable spectroscopic handle with which to monitor reactions. |
| first_indexed | 2024-03-06T20:20:03Z |
| format | Journal article |
| id | oxford-uuid:2d7c1d4e-9e1d-4b72-a31c-3e2197131f1b |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:20:03Z |
| publishDate | 2014 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:2d7c1d4e-9e1d-4b72-a31c-3e2197131f1b2022-03-26T12:43:14ZFrom clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2d7c1d4e-9e1d-4b72-a31c-3e2197131f1bEnglishSymplectic Elements at OxfordAmerican Chemical Society2014Turbervill, RGoicoechea, JThe controlled chemical activation of white phosphorus is a versatile, albeit often unpredictable, route to phosphorus containing species of varied nuclearities. The product distribution is particularly dependent on stoichiometry, temperature, and solvent. Low boiling point, highly polar solvents such as ammonia tend to favor formation of relatively small polyphosphides, whereas higher boiling or less polar solvents tend to favor formation of more highly aggregated anions. Binary solids and molecular anions are inextricably linked by both shared structural motifs and indeed the ability to extract solvated anions from the solid phases themselves. The chemistry of the polyarsenide, polystibide, and polybismuthide analogues is substantially less well developed, no doubt due to the lack of a suitable spectroscopic handle with which to monitor reactions. |
| spellingShingle | Turbervill, R Goicoechea, J From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title | From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title_full | From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title_fullStr | From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title_full_unstemmed | From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title_short | From clusters to unorthodox pnictogen sources: solution-phase reactivity of [E7](3-) (E = P-Sb) anions. |
| title_sort | from clusters to unorthodox pnictogen sources solution phase reactivity of e7 3 e p sb anions |
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