The synthesis of [(eta(6)-Flu*H)Mn(CO)(3)]PF6, and its deprotonation to yield a novel coordination mode of fluorene
The synthesis of [(η6-Flu*H)Mn(CO)3]PF6 is reported. The complex may be deprotonated to give a neutral zwitterionic complex. Instead of deprotonation at the 9-position, as seen in the non-methylated complex, deprotonation of a ring methyl is observed. This yields a previously unknown coordination mo...
| Main Authors: | , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
2007
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| Summary: | The synthesis of [(η6-Flu*H)Mn(CO)3]PF6 is reported. The complex may be deprotonated to give a neutral zwitterionic complex. Instead of deprotonation at the 9-position, as seen in the non-methylated complex, deprotonation of a ring methyl is observed. This yields a previously unknown coordination mode of fluorene, and may be explained on both electronic and steric grounds. © 2007 Elsevier B.V. All rights reserved. |
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