The synthesis of [(eta(6)-Flu*H)Mn(CO)(3)]PF6, and its deprotonation to yield a novel coordination mode of fluorene
The synthesis of [(η6-Flu*H)Mn(CO)3]PF6 is reported. The complex may be deprotonated to give a neutral zwitterionic complex. Instead of deprotonation at the 9-position, as seen in the non-methylated complex, deprotonation of a ring methyl is observed. This yields a previously unknown coordination mo...
Main Authors: | Moss, J, Thomas, J, Cowley, A, O'Hare, D |
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Format: | Journal article |
Language: | English |
Published: |
2007
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