AlMe3 and ZnMe2 adducts of a titanium imido methyl cation: a combined crystallographic, spectroscopic, and DFT study.
A combined experimental and DFT study of the reactions of the titanium imido methyl cation [Ti(NtBu)(Me3[9]aneN3)Me]+ (4+) with AlMe3 and ZnMe2 is described. Reaction of 4+ with AlMe3 gave [Ti(NtBu)(Me3[9]aneN3)(mu-Me)2AlMe2]+ (7+), the first structurally characterized AlMe3 adduct of a transition m...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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