Divacancy superstructures in thermoelectric calcium-doped sodium cobaltate
We have grown single crystals of NaxCayCoO2 and determined their superstructures as a function of composition using neutron and x-ray diffraction. Inclusion of Ca2+ stabilizes a single superstructure across a wide range of temperatures and concentrations. The superstructure in the Na+ layers is base...
Hauptverfasser: | Porter, D, Roger, M, Gutmann, M, Uthayakumar, S, Prabhakaran, D, Boothroyd, A, Pandiyan, MS, Goff, J |
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Format: | Journal article |
Sprache: | English |
Veröffentlicht: |
American Physical Society
2014
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