Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex
The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion...
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| Hlavní autoři: |
Fujihara, T,
Rees, N,
Umakoshi, K,
Tachibana, J,
Sasaki, Y,
McFarlane, W,
Imamura, T |
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| Médium: | Journal article
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| Jazyk: | English |
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| Vydáno: |
2000
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