Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates: Ti=N(α) cycloaddition, Ti=N(α) insertion and N(α) -N(β) bond cleavage.
We report a range of new transformations of the diamide-amine supported Ti=NNPh(2) functional group with a variety of unsaturated substrates, along with DFT studies of the key mechanisms. Reaction of [Ti(N(2) N(py) )(NNPh(2) )(py)] (4, N(2) N(py) =(2-NC(5) H(4) )CMe(CH(2) NSiMe(3) )(2) ; py=pyridine...
প্রধান লেখক: | Schofield, A, Nova, A, Selby, J, Schwarz, A, Clot, E, Mountford, P |
---|---|
বিন্যাস: | Journal article |
ভাষা: | English |
প্রকাশিত: |
2011
|
অনুরূপ উপাদানগুলি
অনুরূপ উপাদানগুলি
-
Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: Ti==N(α) Cycloaddition, Ti==N(α) Insertion and N(α)--N(β) Bond Cleavage.
অনুযায়ী: Schofield, A, অন্যান্য
প্রকাশিত: (2010) -
Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates: Ti=N-alpha Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions
অনুযায়ী: Tiong, P, অন্যান্য
প্রকাশিত: (2011) -
Site selectivity and reversibility in the reactions of titanium hydrazides with Si-H, Si-X, C-X and H+ reagents: Ti=N(α) 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis.
অনুযায়ী: Tiong, P, অন্যান্য
প্রকাশিত: (2012) -
Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.
অনুযায়ী: Schwarz, A, অন্যান্য
প্রকাশিত: (2011) -
Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.
অনুযায়ী: Tiong, P, অন্যান্য
প্রকাশিত: (2010)