Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra

Sub-millimetre spectra measured with Herschel's SPIRE Fourier Transform Spectrometer were used to search for ammonia (NH3) in Titan's stratosphere. Observations were taken during 2010 and 2011, just after Titan's northern spring equinox, which occurred in mid-2009. In our analysis we...

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Main Authors: Teanby, N, Irwin, P, Nixon, C, Courtin, R, Swinyard, B, Moreno, R, Lellouch, E, Rengel, M, Hartogh, P
Format: Journal article
Language:English
Published: 2013
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author Teanby, N
Irwin, P
Nixon, C
Courtin, R
Swinyard, B
Moreno, R
Lellouch, E
Rengel, M
Hartogh, P
author_facet Teanby, N
Irwin, P
Nixon, C
Courtin, R
Swinyard, B
Moreno, R
Lellouch, E
Rengel, M
Hartogh, P
author_sort Teanby, N
collection OXFORD
description Sub-millimetre spectra measured with Herschel's SPIRE Fourier Transform Spectrometer were used to search for ammonia (NH3) in Titan's stratosphere. Observations were taken during 2010 and 2011, just after Titan's northern spring equinox, which occurred in mid-2009. In our analysis we used high spectral resolution data (0.074 cm-1 apodised) from the SPIRE shortwave spectrometer array (SSW), which provided the best possible signal-to-noise ratio for detecting any NH3 emission features. These data have the most sensitivity to NH3 spectral emission of any currently available observations, although despite this we did not detect any significant emission features above the noise. However, we can place an improved 3-sigma upper limit on NH3 abundance of <0.19ppb for altitudes 65-110 km (75 km peak sensitivity), or alternatively a column abundance of <1.23×1015molecules/cm2. These observations provide modest constraint for future photochemical models and are consistent with most current stratospheric predictions. Scaling of photochemical model profiles, in order to fit elevated abundances observed at 1100 km by Cassini's INMS instrument, are for the most part also consistent with our observations. © 2012 Elsevier Ltd.
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spelling oxford-uuid:2fcee0fe-c8d9-4ff9-b817-ddbb7c10b3b12022-03-26T12:57:43ZConstraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectraJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2fcee0fe-c8d9-4ff9-b817-ddbb7c10b3b1EnglishSymplectic Elements at Oxford2013Teanby, NIrwin, PNixon, CCourtin, RSwinyard, BMoreno, RLellouch, ERengel, MHartogh, PSub-millimetre spectra measured with Herschel's SPIRE Fourier Transform Spectrometer were used to search for ammonia (NH3) in Titan's stratosphere. Observations were taken during 2010 and 2011, just after Titan's northern spring equinox, which occurred in mid-2009. In our analysis we used high spectral resolution data (0.074 cm-1 apodised) from the SPIRE shortwave spectrometer array (SSW), which provided the best possible signal-to-noise ratio for detecting any NH3 emission features. These data have the most sensitivity to NH3 spectral emission of any currently available observations, although despite this we did not detect any significant emission features above the noise. However, we can place an improved 3-sigma upper limit on NH3 abundance of <0.19ppb for altitudes 65-110 km (75 km peak sensitivity), or alternatively a column abundance of <1.23×1015molecules/cm2. These observations provide modest constraint for future photochemical models and are consistent with most current stratospheric predictions. Scaling of photochemical model profiles, in order to fit elevated abundances observed at 1100 km by Cassini's INMS instrument, are for the most part also consistent with our observations. © 2012 Elsevier Ltd.
spellingShingle Teanby, N
Irwin, P
Nixon, C
Courtin, R
Swinyard, B
Moreno, R
Lellouch, E
Rengel, M
Hartogh, P
Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title_full Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title_fullStr Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title_full_unstemmed Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title_short Constraints on Titan's middle atmosphere ammonia abundance from Herschel/SPIRE sub-millimetre spectra
title_sort constraints on titan s middle atmosphere ammonia abundance from herschel spire sub millimetre spectra
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