Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission
Band-gap states in V-doped TiO2 have been studied by photoemission spectroscopy over a range of photon energies encompassing the Ti 3p and V 3p core thresholds. The states show resonant enhancement at photon energies significantly higher than found for Ti 3d states introduced into TiO2 by oxygen def...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Physical Society
1997
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| Subjects: |
| _version_ | 1797061415874330624 |
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| author | Morris, D Dixon, R Jones, F Dou, Y Egdell, R Downes, S Beamson, G |
| author_facet | Morris, D Dixon, R Jones, F Dou, Y Egdell, R Downes, S Beamson, G |
| author_sort | Morris, D |
| collection | OXFORD |
| description | Band-gap states in V-doped TiO2 have been studied by photoemission spectroscopy over a range of photon energies encompassing the Ti 3p and V 3p core thresholds. The states show resonant enhancement at photon energies significantly higher than found for Ti 3d states introduced into TiO2 by oxygen deficiency or alkali-metal adsorbates. This demonstrates that the gap states relate to electrons trapped on dopant V cations rather than host Ti cations. |
| first_indexed | 2024-03-06T20:30:50Z |
| format | Journal article |
| id | oxford-uuid:30f7e80c-b7f0-4992-9479-9c7a82ffe84e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:30:50Z |
| publishDate | 1997 |
| publisher | American Physical Society |
| record_format | dspace |
| spelling | oxford-uuid:30f7e80c-b7f0-4992-9479-9c7a82ffe84e2022-03-26T13:04:59ZNature of band-gap states in V-doped TiO2 revealed by resonant photoemissionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:30f7e80c-b7f0-4992-9479-9c7a82ffe84eChemistry & allied sciencesInorganic chemistryEnglishOxford University Research Archive - ValetAmerican Physical Society1997Morris, DDixon, RJones, FDou, YEgdell, RDownes, SBeamson, GBand-gap states in V-doped TiO2 have been studied by photoemission spectroscopy over a range of photon energies encompassing the Ti 3p and V 3p core thresholds. The states show resonant enhancement at photon energies significantly higher than found for Ti 3d states introduced into TiO2 by oxygen deficiency or alkali-metal adsorbates. This demonstrates that the gap states relate to electrons trapped on dopant V cations rather than host Ti cations. |
| spellingShingle | Chemistry & allied sciences Inorganic chemistry Morris, D Dixon, R Jones, F Dou, Y Egdell, R Downes, S Beamson, G Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title | Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title_full | Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title_fullStr | Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title_full_unstemmed | Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title_short | Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission |
| title_sort | nature of band gap states in v doped tio2 revealed by resonant photoemission |
| topic | Chemistry & allied sciences Inorganic chemistry |
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