Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2.
H Box: The clusters [Rh6(PR3)6H 12][BArF4]2 (R = cyclohexyl, iPr; see scheme, pink Rh, orange P) reversibly take up two molecules of H2 under ambient conditions (1 atm H2, 298 K) to give discrete octahedral clusters surrounded by 16 hydride ligands. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH a...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2005
|
| _version_ | 1826265921583316992 |
|---|---|
| author | Brayshaw, S Ingleson, M Green, J Raithby, P Kociok-Köhn, G McIndoe, J Weller, A |
| author_facet | Brayshaw, S Ingleson, M Green, J Raithby, P Kociok-Köhn, G McIndoe, J Weller, A |
| author_sort | Brayshaw, S |
| collection | OXFORD |
| description | H Box: The clusters [Rh6(PR3)6H 12][BArF4]2 (R = cyclohexyl, iPr; see scheme, pink Rh, orange P) reversibly take up two molecules of H2 under ambient conditions (1 atm H2, 298 K) to give discrete octahedral clusters surrounded by 16 hydride ligands. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-06T20:31:09Z |
| format | Journal article |
| id | oxford-uuid:31156122-3645-4479-8cc5-ed0f1512c1cc |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:31:09Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:31156122-3645-4479-8cc5-ed0f1512c1cc2022-03-26T13:05:43ZHolding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:31156122-3645-4479-8cc5-ed0f1512c1ccEnglishSymplectic Elements at Oxford2005Brayshaw, SIngleson, MGreen, JRaithby, PKociok-Köhn, GMcIndoe, JWeller, AH Box: The clusters [Rh6(PR3)6H 12][BArF4]2 (R = cyclohexyl, iPr; see scheme, pink Rh, orange P) reversibly take up two molecules of H2 under ambient conditions (1 atm H2, 298 K) to give discrete octahedral clusters surrounded by 16 hydride ligands. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Brayshaw, S Ingleson, M Green, J Raithby, P Kociok-Köhn, G McIndoe, J Weller, A Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title | Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title_full | Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title_fullStr | Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title_full_unstemmed | Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title_short | Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2. |
| title_sort | holding onto lots of hydrogen a 12 hydride rhodium cluster that reversibly adds two molecules of h2 |
| work_keys_str_mv | AT brayshaws holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT inglesonm holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT greenj holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT raithbyp holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT kociokkohng holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT mcindoej holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 AT wellera holdingontolotsofhydrogena12hydriderhodiumclusterthatreversiblyaddstwomoleculesofh2 |