Chiral selection in the formation of borates from racemic binaphthols and related diols
A series of racemic or stereochemically labile chiral borate anions based on the 2,2′-biphenol motif was investigated. All borates were homochiral in the solid state, although in some cases the heterochiral diastereomers were computed to be thermodynamically preferred (DFT). The crystallographic pre...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2011
|
| Subjects: |
| _version_ | 1797061545549627392 |
|---|---|
| author | Raskatov, J Brown, J Thompson, A |
| author_facet | Raskatov, J Brown, J Thompson, A |
| author_sort | Raskatov, J |
| collection | OXFORD |
| description | A series of racemic or stereochemically labile chiral borate anions based on the 2,2′-biphenol motif was investigated. All borates were homochiral in the solid state, although in some cases the heterochiral diastereomers were computed to be thermodynamically preferred (DFT). The crystallographic preference for the homochiral diastereomer was attributed to its lower bulk, higher molecular symmetry, and the therewith associated better packing ability. |
| first_indexed | 2024-03-06T20:32:43Z |
| format | Journal article |
| id | oxford-uuid:31999dd9-c516-4735-af60-d5641d21ffce |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:32:43Z |
| publishDate | 2011 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:31999dd9-c516-4735-af60-d5641d21ffce2022-03-26T13:08:57ZChiral selection in the formation of borates from racemic binaphthols and related diolsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:31999dd9-c516-4735-af60-d5641d21ffceChemical crystallographySolid state chemistryStructural chemistryCrystallographyEnglishSymplectic Elements at OxfordRoyal Society of Chemistry2011Raskatov, JBrown, JThompson, AA series of racemic or stereochemically labile chiral borate anions based on the 2,2′-biphenol motif was investigated. All borates were homochiral in the solid state, although in some cases the heterochiral diastereomers were computed to be thermodynamically preferred (DFT). The crystallographic preference for the homochiral diastereomer was attributed to its lower bulk, higher molecular symmetry, and the therewith associated better packing ability. |
| spellingShingle | Chemical crystallography Solid state chemistry Structural chemistry Crystallography Raskatov, J Brown, J Thompson, A Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title | Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title_full | Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title_fullStr | Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title_full_unstemmed | Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title_short | Chiral selection in the formation of borates from racemic binaphthols and related diols |
| title_sort | chiral selection in the formation of borates from racemic binaphthols and related diols |
| topic | Chemical crystallography Solid state chemistry Structural chemistry Crystallography |
| work_keys_str_mv | AT raskatovj chiralselectionintheformationofboratesfromracemicbinaphtholsandrelateddiols AT brownj chiralselectionintheformationofboratesfromracemicbinaphtholsandrelateddiols AT thompsona chiralselectionintheformationofboratesfromracemicbinaphtholsandrelateddiols |