Contrasting reactivity of anionic boron- and gallium-containing NHC analogues: E-C vs. E-M bond formation (E = B, Ga).
The anionic Group 13 NHC analogues [(CHNDipp)(2)E](-) (E = B or Ga) display contrasting reactivity towards the half-sandwich titanium imido complex Cp*TiCl(NtBu)py; while the gallium system undergoes salt metathesis yielding the first example of a titanium gallyl compound, the more nucleophilic bory...
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Bibliographic Details
| Main Authors: |
Protchenko, A,
Saleh, L,
Vidovic, D,
Dange, D,
Jones, C,
Mountford, P,
Aldridge, S |
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| Format: | Journal article
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| Language: | English |
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| Published: |
2010
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