Contrasting reactivity of anionic boron- and gallium-containing NHC analogues: E-C vs. E-M bond formation (E = B, Ga).
The anionic Group 13 NHC analogues [(CHNDipp)(2)E](-) (E = B or Ga) display contrasting reactivity towards the half-sandwich titanium imido complex Cp*TiCl(NtBu)py; while the gallium system undergoes salt metathesis yielding the first example of a titanium gallyl compound, the more nucleophilic bory...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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