[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.

The complex [(PPh3)Ag(CB11H6Br6)] 1 is an effective and selective catalyst (0.1 mol% loading) for a hetero-Diels-Alder reaction, which shows a marked dependence on the presence of trace amounts of water, while addition of Ag[Y] [Y = CB11H12, CB11H6Br6, O3SCF3] to a phosphine functionalized support g...

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Main Authors: Hague, C, Patmore, N, Frost, C, Mahon, M, Weller, A
Format: Journal article
Language:English
Published: 2001
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author Hague, C
Patmore, N
Frost, C
Mahon, M
Weller, A
author_facet Hague, C
Patmore, N
Frost, C
Mahon, M
Weller, A
author_sort Hague, C
collection OXFORD
description The complex [(PPh3)Ag(CB11H6Br6)] 1 is an effective and selective catalyst (0.1 mol% loading) for a hetero-Diels-Alder reaction, which shows a marked dependence on the presence of trace amounts of water, while addition of Ag[Y] [Y = CB11H12, CB11H6Br6, O3SCF3] to a phosphine functionalized support gives an efficient and recyclable Lewis acid catalyst for this transformation.
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spelling oxford-uuid:32580cd6-ef12-4264-bcc7-ad517491fb102022-03-26T13:13:24Z[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:32580cd6-ef12-4264-bcc7-ad517491fb10EnglishSymplectic Elements at Oxford2001Hague, CPatmore, NFrost, CMahon, MWeller, AThe complex [(PPh3)Ag(CB11H6Br6)] 1 is an effective and selective catalyst (0.1 mol% loading) for a hetero-Diels-Alder reaction, which shows a marked dependence on the presence of trace amounts of water, while addition of Ag[Y] [Y = CB11H12, CB11H6Br6, O3SCF3] to a phosphine functionalized support gives an efficient and recyclable Lewis acid catalyst for this transformation.
spellingShingle Hague, C
Patmore, N
Frost, C
Mahon, M
Weller, A
[(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title_full [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title_fullStr [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title_full_unstemmed [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title_short [(PPh3)Ag(CB11H6Y6)] (Y = H, Br): highly active, selective and recyclable Lewis acids for a hetero-Diels-Alder reaction.
title_sort pph3 ag cb11h6y6 y h br highly active selective and recyclable lewis acids for a hetero diels alder reaction
work_keys_str_mv AT haguec pph3agcb11h6y6yhbrhighlyactiveselectiveandrecyclablelewisacidsforaheterodielsalderreaction
AT patmoren pph3agcb11h6y6yhbrhighlyactiveselectiveandrecyclablelewisacidsforaheterodielsalderreaction
AT frostc pph3agcb11h6y6yhbrhighlyactiveselectiveandrecyclablelewisacidsforaheterodielsalderreaction
AT mahonm pph3agcb11h6y6yhbrhighlyactiveselectiveandrecyclablelewisacidsforaheterodielsalderreaction
AT wellera pph3agcb11h6y6yhbrhighlyactiveselectiveandrecyclablelewisacidsforaheterodielsalderreaction