Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation.
The crystal structure of a cyanine dye rotaxane shows that the cyclodextrin is tightly threaded round the polymethine bridge of the dye; encapsulation dramatically increases the kinetic chemical stability of the radicals formed on oxidation and reduction of the dye, making it possible to observe the...
| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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| _version_ | 1826266278634979328 |
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| author | Yau, C Pascu, S Odom, SA Warren, J Klotz, E Frampton, M Williams, C Coropceanu, V Kuimova, M Phillips, D Barlow, S Brédas, J Marder, SR Millar, V Anderson, H |
| author_facet | Yau, C Pascu, S Odom, SA Warren, J Klotz, E Frampton, M Williams, C Coropceanu, V Kuimova, M Phillips, D Barlow, S Brédas, J Marder, SR Millar, V Anderson, H |
| author_sort | Yau, C |
| collection | OXFORD |
| description | The crystal structure of a cyanine dye rotaxane shows that the cyclodextrin is tightly threaded round the polymethine bridge of the dye; encapsulation dramatically increases the kinetic chemical stability of the radicals formed on oxidation and reduction of the dye, making it possible to observe the rotaxane radical dication by ESR and UV-vis-NIR spectroscopy. |
| first_indexed | 2024-03-06T20:36:29Z |
| format | Journal article |
| id | oxford-uuid:32ce202a-e9cb-4666-9ce6-17ce71894a5d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T20:36:29Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:32ce202a-e9cb-4666-9ce6-17ce71894a5d2022-03-26T13:16:32ZStabilisation of a heptamethine cyanine dye by rotaxane encapsulation.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:32ce202a-e9cb-4666-9ce6-17ce71894a5dEnglishSymplectic Elements at Oxford2008Yau, CPascu, SOdom, SAWarren, JKlotz, EFrampton, MWilliams, CCoropceanu, VKuimova, MPhillips, DBarlow, SBrédas, JMarder, SRMillar, VAnderson, HThe crystal structure of a cyanine dye rotaxane shows that the cyclodextrin is tightly threaded round the polymethine bridge of the dye; encapsulation dramatically increases the kinetic chemical stability of the radicals formed on oxidation and reduction of the dye, making it possible to observe the rotaxane radical dication by ESR and UV-vis-NIR spectroscopy. |
| spellingShingle | Yau, C Pascu, S Odom, SA Warren, J Klotz, E Frampton, M Williams, C Coropceanu, V Kuimova, M Phillips, D Barlow, S Brédas, J Marder, SR Millar, V Anderson, H Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title | Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title_full | Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title_fullStr | Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title_full_unstemmed | Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title_short | Stabilisation of a heptamethine cyanine dye by rotaxane encapsulation. |
| title_sort | stabilisation of a heptamethine cyanine dye by rotaxane encapsulation |
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